BROWSE

Related Scientist

Zhang, Jianbo's photo.

Zhang, Jianbo
분자활성 촉매반응 연구단
more info

ITEM VIEW & DOWNLOAD

cine-Silylative Ring-Opening of α-Methyl Azacycles Enabled by the Silylium-Induced C-N Bond Cleavage

DC Field Value Language
dc.contributor.authorJianbo Zhang-
dc.contributor.authorSukbok Chang-
dc.date.accessioned2020-12-22T02:57:25Z-
dc.date.accessioned2020-12-22T02:57:25Z-
dc.date.available2020-12-22T02:57:25Z-
dc.date.available2020-12-22T02:57:25Z-
dc.date.created2020-09-09-
dc.date.issued2020-07-
dc.identifier.issn0002-7863-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/7767-
dc.description.abstractDescribed herein is the development of a borane-catalyzed cine-silylative ring-opening of α-methyl azacycles. This transformation involves four-step cascade processes: (i) exo-dehydrogenation of alicyclic amine, (ii) hydrosilylation of the resultant enamine, (iii) silylium-induced cis-β-amino elimination to open the ring skeleton, and (iv) hydrosilylation of the terminal olefin. The present borane catalysis also works efficiently for the C-N bond cleavage of acyclic tertiary amines. On the basis of experimental and computational studies, the silicon atom was elucidated to play a pivotal role in the β-amino elimination step © 2020 American Chemical Society-
dc.description.uri1-
dc.language영어-
dc.publisherAMER CHEMICAL SOC-
dc.subjectFRUSTRATED LEWIS PAIRS-
dc.subjectNITROGEN-
dc.subjectSILICON-
dc.subjectFUNCTIONALIZATION-
dc.subjectACTIVATION-
dc.subjectREDUCTION-
dc.subjectROUTE-
dc.subjectHYDROSILYLATION-
dc.titlecine-Silylative Ring-Opening of α-Methyl Azacycles Enabled by the Silylium-Induced C-N Bond Cleavage-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000555420600006-
dc.identifier.scopusid2-s2.0-85088489070-
dc.identifier.rimsid72812-
dc.contributor.affiliatedAuthorJianbo Zhang-
dc.contributor.affiliatedAuthorSukbok Chang-
dc.identifier.doi10.1021/jacs.0c05241-
dc.identifier.bibliographicCitationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.142, no.29, pp.12585 - 12590-
dc.citation.titleJOURNAL OF THE AMERICAN CHEMICAL SOCIETY-
dc.citation.volume142-
dc.citation.number29-
dc.citation.startPage12585-
dc.citation.endPage12590-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.subject.keywordPlusFRUSTRATED LEWIS PAIRS-
dc.subject.keywordPlusNITROGEN-
dc.subject.keywordPlusSILICON-
dc.subject.keywordPlusFUNCTIONALIZATION-
dc.subject.keywordPlusACTIVATION-
dc.subject.keywordPlusREDUCTION-
dc.subject.keywordPlusROUTE-
dc.subject.keywordPlusHYDROSILYLATION-
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
Files in This Item:
There are no files associated with this item.

qrcode

  • facebook

    twitter

  • Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
해당 아이템을 이메일로 공유하기 원하시면 인증을 거치시기 바랍니다.

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

Browse