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분자활성촉매반응연구단
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Double Hydroboration of Quinolines via Borane Catalysis: Diastereoselective One Pot Synthesis of 3-Hydroxytetrahydroquinolines

DC Field Value Language
dc.contributor.authorKim, E-
dc.contributor.authorHyun Ji Jeon-
dc.contributor.authorSehoon Park-
dc.contributor.authorSukbok Chang-
dc.date.available2020-10-14T08:15:40Z-
dc.date.created2019-10-21-
dc.date.issued2020-01-
dc.identifier.issn1615-4150-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/7269-
dc.description.abstractDescribed herein is an organoborane-catalysed consecutive borylative reduction of quinolines and isoquinolines to furnish tetrahydro(iso)quinolines bearing a C(sp(3))-B bond beta to the nitrogen atom. The installed C-B bond is oxidatively transformed to the hydroxy group in one pot. The present double hydroboration is proposed to proceed via a stepwise ionic mechanism involving a boronium ion. The stereo-outcome was found to be dependent on the position (C2 vs C4) of the substituents in quinolines. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim-
dc.description.uri1-
dc.language영어-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectLewis acidic borane-
dc.subjecthydroboration-
dc.subjectconsecutive reaction-
dc.subjectionic mechanism-
dc.subjectdiastereoselectivity-
dc.titleDouble Hydroboration of Quinolines via Borane Catalysis: Diastereoselective One Pot Synthesis of 3-Hydroxytetrahydroquinolines-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000488580800001-
dc.identifier.scopusid2-s2.0-85074461772-
dc.identifier.rimsid70323-
dc.contributor.affiliatedAuthorHyun Ji Jeon-
dc.contributor.affiliatedAuthorSehoon Park-
dc.contributor.affiliatedAuthorSukbok Chang-
dc.identifier.doi10.1002/adsc.201901050-
dc.identifier.bibliographicCitationADVANCED SYNTHESIS & CATALYSIS, v.362, no.2, pp.308 - 313-
dc.citation.titleADVANCED SYNTHESIS & CATALYSIS-
dc.citation.volume362-
dc.citation.number2-
dc.citation.startPage308-
dc.citation.endPage313-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.subject.keywordPlusASYMMETRIC HYDROGENATION-
dc.subject.keywordPlusSILYLATIVE REDUCTION-
dc.subject.keywordPlusREGIOSELECTIVE 1,4-HYDROBORATION-
dc.subject.keywordPlusN-HETEROARENES-
dc.subject.keywordPlusBORENIUM-
dc.subject.keywordPlusCHEMISTRY-
dc.subject.keywordPlusPYRIDINES-
dc.subject.keywordPlusHYDRIDE-
dc.subject.keywordPlusCARBENE-
dc.subject.keywordPlusPAIRS-
dc.subject.keywordAuthorLewis acidic borane-
dc.subject.keywordAuthorhydroboration-
dc.subject.keywordAuthorconsecutive reaction-
dc.subject.keywordAuthorionic mechanism-
dc.subject.keywordAuthordiastereoselectivity-
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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