IBS Publications Repository: Metal-Free Carbocyclization of Homoallylic Silyl Ethers Leading to Cyclopropanes and Cyclobutanes

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IBS Publications RepositoryCenter for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단)1. Journal Papers (저널논문)

Metal-Free Carbocyclization of Homoallylic Silyl Ethers Leading to Cyclopropanes and Cyclobutanes

DC Field	Value	Language
dc.contributor.author	Jianbo Zhang	-
dc.contributor.author	Chinmoy Kumar Hazra	-
dc.contributor.author	Sehoon Park	-
dc.contributor.author	Sukbok Chang	-
dc.date.available	2020-01-31T00:54:48Z	-
dc.date.created	2019-08-20	-
dc.date.issued	2019-09	-
dc.identifier.issn	2193-5807	-
dc.identifier.uri	https://pr.ibs.re.kr/handle/8788114/6868	-
dc.description.abstract	© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, WeinheimWe have developed a Hosomi-Sakurai type carbocyclization of homoallylic silyl ethers in reaction with silyl nucleophiles, catalyzed by Lewis acidic silylium salt. It offers cyclopropane and cyclobutane products with high efficiency and selectivity. A range of silyl nucleophiles could be engaged in this transformation to give small-sized carbocycles incorporating allyl, allenyl, carbonyl, indole or thioether groups. Diastereoselectivity in the cyclobutane formation was observed to be dependent on the steric bulkiness of incoming nucleophiles.	-
dc.description.uri	1	-
dc.language	영어	-
dc.publisher	WILEY-V C H VERLAG GMBH	-
dc.subject	Carbocyclization	-
dc.subject	Cyclobutanes	-
dc.subject	Cyclopropanes	-
dc.subject	Hosomi-Sakurai reaction	-
dc.subject	Silylium ion catalysis	-
dc.title	Metal-Free Carbocyclization of Homoallylic Silyl Ethers Leading to Cyclopropanes and Cyclobutanes	-
dc.type	Article	-
dc.type.rims	ART	-
dc.identifier.wosid	000478513400001	-
dc.identifier.scopusid	2-s2.0-85068874909	-
dc.identifier.rimsid	69109	-
dc.contributor.affiliatedAuthor	Jianbo Zhang	-
dc.contributor.affiliatedAuthor	Chinmoy Kumar Hazra	-
dc.contributor.affiliatedAuthor	Sehoon Park	-
dc.contributor.affiliatedAuthor	Sukbok Chang	-
dc.identifier.doi	10.1002/ajoc.201900270	-
dc.identifier.bibliographicCitation	ASIAN JOURNAL OF ORGANIC CHEMISTRY, v.8, no.9, pp.1637 - 1640	-
dc.citation.title	ASIAN JOURNAL OF ORGANIC CHEMISTRY	-
dc.citation.volume	8	-
dc.citation.number	9	-
dc.citation.startPage	1637	-
dc.citation.endPage	1640	-
dc.description.journalClass	1	-
dc.description.journalRegisteredClass	scie	-
dc.description.journalRegisteredClass	scopus	-
dc.subject.keywordPlus	ALKYL-HALIDES BEARING	-
dc.subject.keywordPlus	C-H	-
dc.subject.keywordPlus	B(C6F5)(3)-CATALYZED ALLYLATION	-
dc.subject.keywordPlus	COPPER(I)-CATALYZED REACTION	-
dc.subject.keywordPlus	REDUCTIVE CARBOCYCLIZATION	-
dc.subject.keywordPlus	NATURAL-PRODUCTS	-
dc.subject.keywordPlus	DERIVATIVES	-
dc.subject.keywordPlus	STRATEGIES	-
dc.subject.keywordPlus	ALLYLTRIMETHYLSILANE	-
dc.subject.keywordPlus	FUNCTIONALIZATION	-
dc.subject.keywordAuthor	Silylium ion catalysis	-
dc.subject.keywordAuthor	Carbocyclization	-
dc.subject.keywordAuthor	Hosomi-Sakurai reaction	-
dc.subject.keywordAuthor	Cyclopropanes	-
dc.subject.keywordAuthor	Cyclobutanes	-