IBS Publications Repository: Asymmetric C-H Functionalization of Cyclopropanes Using an Isoleucine-NH2 Bidentate Directing Group

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IBS Publications RepositoryCenter for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단)1. Journal Papers (저널논문)

Asymmetric C-H Functionalization of Cyclopropanes Using an Isoleucine-NH2 Bidentate Directing Group

DC Field	Value	Language
dc.contributor.author	Jinhee Kim	-
dc.contributor.author	Mikyung Sim	-
dc.contributor.author	Namhoon Kim	-
dc.contributor.author	Sungwoo Hong	-
dc.date.available	2018-07-18T02:09:50Z	-
dc.date.created	2018-03-15	-
dc.date.issued	2015-10	-
dc.identifier.issn	0039-7881	-
dc.identifier.uri	https://pr.ibs.re.kr/handle/8788114/4851	-
dc.description.abstract	The systematic investigation of substrate-bound a-amino acid auxiliaries has resulted in catalytic asymmetric C–H functionalization of cyclopropanes enabled by amino acid amides as chiral bidentate directing groups. The use of an Ile-NH2 auxiliary embedded in the substrate provided excellent levels of asymmetric induction (diastereomeric ratio of up to 72 : 1) in the Pd(II)-catalyzed b-methylene C(sp3)–H bond activation of cyclopropanes and cross-coupling with aryl iodides. This journal is © The Royal Society of Chemistry 2015	-
dc.language	영어	-
dc.publisher	GEORG THIEME VERLAG KG	-
dc.title	Asymmetric C-H Functionalization of Cyclopropanes Using an Isoleucine-NH2 Bidentate Directing Group	-
dc.type	Article	-
dc.type.rims	ART	-
dc.identifier.wosid	000362568400001	-
dc.identifier.scopusid	2-s2.0-84943278596	-
dc.identifier.rimsid	62542	ko
dc.date.tcdate	2018-10-01	-
dc.contributor.affiliatedAuthor	Jinhee Kim	-
dc.contributor.affiliatedAuthor	Mikyung Sim	-
dc.contributor.affiliatedAuthor	Namhoon Kim	-
dc.contributor.affiliatedAuthor	Sungwoo Hong	-
dc.identifier.doi	10.1055/s-0035-1560166	-
dc.identifier.bibliographicCitation	SYNTHESIS-STUTTGART, v.47, no.19, pp.A136 - A139	-
dc.relation.isPartOf	SYNTHESIS-STUTTGART	-
dc.citation.title	SYNTHESIS-STUTTGART	-
dc.citation.volume	47	-
dc.citation.number	19	-
dc.citation.startPage	A136	-
dc.citation.endPage	A139	-
dc.date.scptcdate	2018-10-01	-
dc.description.scptc	40	-
dc.description.journalClass	1	-
dc.description.journalClass	1	-
dc.description.journalRegisteredClass	scie	-
dc.description.journalRegisteredClass	scopus	-
dc.relation.journalWebOfScienceCategory	Chemistry, Organic	-