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분자활성촉매반응연구단
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Asymmetric C-H Functionalization of Cyclopropanes Using an Isoleucine-NH2 Bidentate Directing Group

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dc.contributor.authorJinhee Kim-
dc.contributor.authorMikyung Sim-
dc.contributor.authorNamhoon Kim-
dc.contributor.authorSungwoo Hong-
dc.date.available2018-07-18T02:09:50Z-
dc.date.created2018-03-15-
dc.date.issued2015-10-
dc.identifier.issn0039-7881-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/4851-
dc.description.abstractThe systematic investigation of substrate-bound a-amino acid auxiliaries has resulted in catalytic asymmetric C–H functionalization of cyclopropanes enabled by amino acid amides as chiral bidentate directing groups. The use of an Ile-NH2 auxiliary embedded in the substrate provided excellent levels of asymmetric induction (diastereomeric ratio of up to 72 : 1) in the Pd(II)-catalyzed b-methylene C(sp3)–H bond activation of cyclopropanes and cross-coupling with aryl iodides. This journal is © The Royal Society of Chemistry 2015-
dc.language영어-
dc.publisherGEORG THIEME VERLAG KG-
dc.titleAsymmetric C-H Functionalization of Cyclopropanes Using an Isoleucine-NH2 Bidentate Directing Group-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000362568400001-
dc.identifier.scopusid2-s2.0-84943278596-
dc.identifier.rimsid62542ko
dc.date.tcdate2018-10-01-
dc.contributor.affiliatedAuthorJinhee Kim-
dc.contributor.affiliatedAuthorMikyung Sim-
dc.contributor.affiliatedAuthorNamhoon Kim-
dc.contributor.affiliatedAuthorSungwoo Hong-
dc.identifier.doi10.1055/s-0035-1560166-
dc.identifier.bibliographicCitationSYNTHESIS-STUTTGART, v.47, no.19, pp.A136 - A139-
dc.relation.isPartOfSYNTHESIS-STUTTGART-
dc.citation.titleSYNTHESIS-STUTTGART-
dc.citation.volume47-
dc.citation.number19-
dc.citation.startPageA136-
dc.citation.endPageA139-
dc.date.scptcdate2018-10-01-
dc.description.scptc40-
dc.description.journalClass1-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalWebOfScienceCategoryChemistry, Organic-
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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H_s-0035-1560166_Asymmetric C-H foundation_페이지 기사.pdfDownload

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