IBS Publications Repository: Reductive Carbocyclization of Homoallylic Alcohols to syn-Cyclobutanes by a Boron-Catalyzed Dual Ring-Closing Pathway

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IBS Publications RepositoryCenter for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단)1. Journal Papers (저널논문)

Reductive Carbocyclization of Homoallylic Alcohols to syn-Cyclobutanes by a Boron-Catalyzed Dual Ring-Closing Pathway

DC Field	Value	Language
dc.contributor.author	ChinmoyKumar Hazra	-
dc.contributor.author	Jinhoon Jeong	-
dc.contributor.author	Hyunjoong Kim	-
dc.contributor.author	Mu-Hyun Baik	-
dc.contributor.author	Sehoon Park	-
dc.contributor.author	Sukbok Chang	-
dc.date.available	2018-07-18T02:04:38Z	-
dc.date.created	2018-04-16	-
dc.date.issued	2018-03	-
dc.identifier.issn	1433-7851	-
dc.identifier.uri	https://pr.ibs.re.kr/handle/8788114/4604	-
dc.description.abstract	The organoborane-catalyzed reductive carbocyclization of homoallylic alcohols has been developed by using hydrosilanes as reducing reagents to provide a range of 1,2-disubstituted arylcyclobutanes. The reaction proceeds in a cis-selective manner with high efficiency under mild conditions. Mechanistic studies, including deuterium scrambling and Hammett studies, and DFT calculations, suggest a dual ring-closing pathway. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinhei	-
dc.description.uri	1	-
dc.language	영어	-
dc.publisher	WILEY-V C H VERLAG GMBH	-
dc.subject	carbocyclization	-
dc.subject	cyclobutanes	-
dc.subject	homoallylic alcohols	-
dc.subject	neighboring-group effects	-
dc.subject	ring-closing	-
dc.title	Reductive Carbocyclization of Homoallylic Alcohols to syn-Cyclobutanes by a Boron-Catalyzed Dual Ring-Closing Pathway	-
dc.type	Article	-
dc.type.rims	ART	-
dc.identifier.wosid	000426252400030	-
dc.identifier.scopusid	2-s2.0-85041598605	-
dc.identifier.rimsid	63037	ko
dc.contributor.affiliatedAuthor	ChinmoyKumar Hazra	-
dc.contributor.affiliatedAuthor	Jinhoon Jeong	-
dc.contributor.affiliatedAuthor	Hyunjoong Kim	-
dc.contributor.affiliatedAuthor	Mu-Hyun Baik	-
dc.contributor.affiliatedAuthor	Sehoon Park	-
dc.contributor.affiliatedAuthor	Sukbok Chang	-
dc.identifier.doi	10.1002/anie.201713285	-
dc.identifier.bibliographicCitation	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.57, no.10, pp.2692 - 2696	-
dc.citation.title	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION	-
dc.citation.volume	57	-
dc.citation.number	10	-
dc.citation.startPage	2692	-
dc.citation.endPage	2696	-
dc.embargo.liftdate	9999-12-31	-
dc.embargo.terms	9999-12-31	-
dc.description.journalClass	1	-
dc.description.journalRegisteredClass	scie	-
dc.description.journalRegisteredClass	scopus	-
dc.subject.keywordAuthor	carbocyclization	-
dc.subject.keywordAuthor	cyclobutanes	-
dc.subject.keywordAuthor	homoallylic alcohols	-
dc.subject.keywordAuthor	neighboring-group effects	-
dc.subject.keywordAuthor	ring-closing	-