IBS Publications Repository: Selective C−O Bond Cleavage of Sugars with Hydrosilanes Catalyzed by Piers’ Borane Generated In Situ

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IBS Publications RepositoryCenter for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단)1. Journal Papers (저널논문)

Selective C−O Bond Cleavage of Sugars with Hydrosilanes Catalyzed by Piers’ Borane Generated In Situ

DC Field	Value	Language
dc.contributor.author	Jianbo Zhang	-
dc.contributor.author	Sehoon Park	-
dc.contributor.author	Sukbok Chang	-
dc.date.available	2018-01-09T07:12:54Z	-
dc.date.created	2017-11-17	-
dc.date.issued	2017-10	-
dc.identifier.issn	1433-7851	-
dc.identifier.uri	https://pr.ibs.re.kr/handle/8788114/4219	-
dc.description.abstract	Described herein is the selective reduction of sugars with hydrosilanes catalyzed by using Piers’ borane [(C6F5)2BH] generated in situ. The hydrosilylative C−O bond cleavage of silyl-protected mono- and disaccharides in the presence of a (C6F5)2BH catalyst, generated in situ from (C6F5)2BOH, takes place with excellent chemo- and regioselectivities to provide a range of polyols. A study of the substituent effects of sugars on the catalytic activity and selectivity revealed that the steric environment around the anomeric carbon (C1) is crucial. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinhei	-
dc.description.uri	1	-
dc.language	영어	-
dc.publisher	WILEY-V C H VERLAG GMBH	-
dc.subject	bond cleavage	-
dc.subject	chemoselectivity	-
dc.subject	hydrosilylative reduction	-
dc.subject	Piers’ borane	-
dc.subject	sugars	-
dc.title	Selective C−O Bond Cleavage of Sugars with Hydrosilanes Catalyzed by Piers’ Borane Generated In Situ	-
dc.type	Article	-
dc.type.rims	ART	-
dc.identifier.wosid	000413314800038	-
dc.identifier.scopusid	2-s2.0-85030479396	-
dc.identifier.rimsid	60911	ko
dc.date.tcdate	2018-10-01	-
dc.contributor.affiliatedAuthor	Jianbo Zhang	-
dc.contributor.affiliatedAuthor	Sehoon Park	-
dc.contributor.affiliatedAuthor	Sukbok Chang	-
dc.identifier.doi	10.1002/anie.201708109	-
dc.identifier.bibliographicCitation	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.56, no.44, pp.13757 - 13761	-
dc.citation.title	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION	-
dc.citation.volume	56	-
dc.citation.number	44	-
dc.citation.startPage	13757	-
dc.citation.endPage	13761	-
dc.date.scptcdate	2018-10-01	-
dc.description.wostc	3	-
dc.description.scptc	3	-
dc.embargo.liftdate	9999-12-31	-
dc.embargo.terms	9999-12-31	-
dc.description.journalClass	1	-
dc.description.journalRegisteredClass	scie	-
dc.description.journalRegisteredClass	scopus	-
dc.subject.keywordAuthor	bond cleavage	-
dc.subject.keywordAuthor	chemoselectivity	-
dc.subject.keywordAuthor	hydrosilylative reduction	-
dc.subject.keywordAuthor	Piers’ borane	-
dc.subject.keywordAuthor	sugars	-