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IBS Publications RepositoryCenter for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단)1. Journal Papers (저널논문)
Diastereoselective Construction of α-Silyltetrahydropyranols through Silyl-Oxa-Prins Cyclization
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- Title
- Diastereoselective Construction of α-Silyltetrahydropyranols through Silyl-Oxa-Prins Cyclization
- Author(s)
- Narasimhulu Gandhamsetty; Soyeon Jee; Sukbok Chang
- Subject
- Aldehydes, ; Cyclization, ; Diastereoselectivity, ; Oxygen heterocycles, ; Silicon
- Publication Date
- 2017-01
- Journal
- EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, v.2017, no.4, pp.933 - 938
- Publisher
- WILEY-V C H VERLAG GMBH
- Abstract
- The Brønsted acid mediated selective silyl-oxa-Prins cyclization of α-silyloxy homoallylsilanes with various aldehydes was achieved. Synthetically valuable α-silyltetrahydropyranol products were obtained in high yields with excellent diastereoselectivities. Both syn- and anti-isomeric tetrahydropyranols were selectively obtained by tuning the olefinic geometry of the substrates. The procedure is operationally simple and convenient to perform even on a large scale under mild conditions. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinhei
- ISSN
- 1434-193X
- Appears in Collections:
- Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
- Files in This Item:
- Gandhamsetty_et_al-2017-European_Journal_of_Organic_Chemistry.pdfDownload
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