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분자활성촉매반응연구단
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Selective cyclization of arylnitrones to indolines under external oxidant-free conditions: Dual role of Rh(III) catalyst in the C-H activation and oxygen atom transfer

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dc.contributor.authorRamesh B. Dateer-
dc.contributor.authorSukbok Chang-
dc.date.available2016-01-07T09:14:28Z-
dc.date.created2015-05-18-
dc.date.issued2015-04-
dc.identifier.issn0002-7863-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/2071-
dc.description.abstractThe first example of Rh(III)-catalyzed cyclization of arylnitrones to indolines under external oxidant-free conditions is presented. An intermolecular coupling of arylnitrones with internal alkynes is made possible by the dual role of the Cp∗Rh(III) catalyst mediating both the C-H bond activation and O-atom transfer. Synthetically important and pharmacologically privileged indoline derivatives were obtained in good yields with high diastereoselectivity. © 2015 American Chemical Society-
dc.description.uri1-
dc.language영어-
dc.publisherAMER CHEMICAL SOC-
dc.titleSelective cyclization of arylnitrones to indolines under external oxidant-free conditions: Dual role of Rh(III) catalyst in the C-H activation and oxygen atom transfer-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000353606700009-
dc.identifier.scopusid2-s2.0-84928494419-
dc.identifier.rimsid19608ko
dc.date.tcdate2018-10-01-
dc.contributor.affiliatedAuthorRamesh B. Dateer-
dc.contributor.affiliatedAuthorSukbok Chang-
dc.identifier.doi10.1021/jacs.5b01065-
dc.identifier.bibliographicCitationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.137, no.15, pp.4908 - 4911-
dc.citation.titleJOURNAL OF THE AMERICAN CHEMICAL SOCIETY-
dc.citation.volume137-
dc.citation.number15-
dc.citation.startPage4908-
dc.citation.endPage4911-
dc.date.scptcdate2018-10-01-
dc.description.wostc86-
dc.description.scptc89-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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