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Direct C-H amination of arenes with alkyl azides under rhodium catalysis

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Title
Direct C-H amination of arenes with alkyl azides under rhodium catalysis
Author(s)
Kwangmin Shin; Yunjung Baek; Sukbok Chang
Subject
alkyl nitrenoids, ; Aniline derivatives, ; azides, ; C-H amination, ; Rhodium catalysis, ; Aniline, ; Aromatic compounds, ; Catalysis, ; Functional groups, ; Ketones, ; Rhodium, ; Nitrogen compounds
Publication Date
2013-07
Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.52, no.31, pp.8031 - 8036
Publisher
WILEY-V C H VERLAG GMBH
Abstract
New horizons in the utility of azides: The rhodium-catalyzed intermolecular direct C-H amination of arenes with alkyl azides provides a convenient route to N-alkyl anilines (see scheme; DG=directing group). Alkyl azides with a wide range of functional groups reacted readily with various substrates, including benzamides, aromatic ketones, and flavones. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
URI
https://pr.ibs.re.kr/handle/8788114/1292
DOI
10.1002/anie.201302784
ISSN
1433-7851
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
Files in This Item:
2013-07-29-Angewandte Chemie-Direct C-H Amination.pdfDownload

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