Versatile Utility of Cp∗Co(III) Catalysts in C-H Amination under Inner-and Outer-sphere Pathway
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Jeonghyo Lee | - |
dc.contributor.author | Sukbok Chang | - |
dc.date.accessioned | 2023-01-26T02:18:55Z | - |
dc.date.available | 2023-01-26T02:18:55Z | - |
dc.date.created | 2023-01-11 | - |
dc.date.issued | 2023-07 | - |
dc.identifier.issn | 0936-5214 | - |
dc.identifier.uri | https://pr.ibs.re.kr/handle/8788114/12445 | - |
dc.description.abstract | This Account describes the recent advances in our research program toward the development of cobalt-catalyzed C-H amidation reactions. In particular, synthetic versatilities of obtainable amino products shown to be achieved on the basis of two distinctive mechanistic scaffolds; inner-and outer-sphere pathways. It highlights our approaches to transit the modes C-N bond formation by introduction of bidentate LX-Type ligands into Cp∗Co(III) precursors, thereby broadly expanding the scope of amination reactions. 1 Introduction 2 Cp∗Co-Catalyzed Inner-sphere C-H Amidation 3 Cp∗Co-Catalyzed Outer-sphere C-H Amidation 3.1 C(sp2)-N Bond Formation 3.2 C(sp3)-N Bond Formation 4 Conclusion. © 2022 Georg Thieme Verlag. All rights reserved. | - |
dc.language | 영어 | - |
dc.publisher | Georg Thieme Verlag | - |
dc.title | Versatile Utility of Cp∗Co(III) Catalysts in C-H Amination under Inner-and Outer-sphere Pathway | - |
dc.type | Article | - |
dc.type.rims | ART | - |
dc.identifier.wosid | 000912143300001 | - |
dc.identifier.scopusid | 2-s2.0-85144981348 | - |
dc.identifier.rimsid | 79663 | - |
dc.contributor.affiliatedAuthor | Jeonghyo Lee | - |
dc.contributor.affiliatedAuthor | Sukbok Chang | - |
dc.identifier.doi | 10.1055/a-1987-6464 | - |
dc.identifier.bibliographicCitation | Synlett, v.34, no.12, pp.1356 - 1366 | - |
dc.relation.isPartOf | Synlett | - |
dc.citation.title | Synlett | - |
dc.citation.volume | 34 | - |
dc.citation.number | 12 | - |
dc.citation.startPage | 1356 | - |
dc.citation.endPage | 1366 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.subject.keywordPlus | AMIDO TRANSFER | - |
dc.subject.keywordPlus | GAMMA-LACTAMS | - |
dc.subject.keywordPlus | ACYL AZIDES | - |
dc.subject.keywordPlus | AMIDATION | - |
dc.subject.keywordPlus | FUNCTIONALIZATION | - |
dc.subject.keywordPlus | ARENES | - |
dc.subject.keywordPlus | MILD | - |
dc.subject.keywordPlus | ACTIVATION | - |
dc.subject.keywordPlus | COMPLEX | - |
dc.subject.keywordPlus | REACTIVITY | - |
dc.subject.keywordAuthor | C-H amidation | - |
dc.subject.keywordAuthor | chelation-Assisted amidation | - |
dc.subject.keywordAuthor | Cobalt catalysis | - |
dc.subject.keywordAuthor | nitrenoid insertion | - |
dc.subject.keywordAuthor | site-selective amidation | - |