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Jeonghyo, Lee
분자활성 촉매반응 연구단
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Cobalt-Nitrenoid Insertion-Mediated Amidative Carbon Rearrangement via Alkyl-Walking on Arenes

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dc.contributor.authorJeonghyo Lee-
dc.contributor.authorBora Kang-
dc.contributor.authorDongwook Kim-
dc.contributor.authorJia Lee-
dc.contributor.authorSukbok Chang-
dc.date.accessioned2021-12-16T01:30:15Z-
dc.date.available2021-12-16T01:30:15Z-
dc.date.created2021-12-15-
dc.date.issued2021-11-10-
dc.identifier.issn0002-7863-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/10852-
dc.description.abstract© We herein disclose the Cp*Co(III)(LX)-catalyzed amidative alkyl migration using 2,6-disubstituted phenyl azidoformates. Upon the cobalt-nitrenoid insertion toward the substituted ortho carbon, an arenium cationic species bearing a quaternary carbon is generated, and a subsequent alkyl migration process is suggested to occur through an unforeseen alkyl-walking mechanism. A quinolinol ligand of the cobalt catalyst system is proposed to facilitate the final product-releasing rearomatization process by serving as an internal base. This new mechanistic mode enabled both [1,2]- and [1,4]-alkyl rearrangements to allow the structural variation of N-heterocyclic compounds.-
dc.language영어-
dc.publisherAmerican Chemical Society-
dc.titleCobalt-Nitrenoid Insertion-Mediated Amidative Carbon Rearrangement via Alkyl-Walking on Arenes-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000718279300008-
dc.identifier.scopusid2-s2.0-85118778201-
dc.identifier.rimsid76866-
dc.contributor.affiliatedAuthorJeonghyo Lee-
dc.contributor.affiliatedAuthorBora Kang-
dc.contributor.affiliatedAuthorDongwook Kim-
dc.contributor.affiliatedAuthorJia Lee-
dc.contributor.affiliatedAuthorSukbok Chang-
dc.identifier.doi10.1021/jacs.1c10138-
dc.identifier.bibliographicCitationJournal of the American Chemical Society, v.143, no.44, pp.18406 - 18412-
dc.relation.isPartOfJournal of the American Chemical Society-
dc.citation.titleJournal of the American Chemical Society-
dc.citation.volume143-
dc.citation.number44-
dc.citation.startPage18406-
dc.citation.endPage18412-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalClass1-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.subject.keywordPlusC-H AMIDATION-
dc.subject.keywordPlus3-COMPOUND EQUILIBRATIONS-
dc.subject.keywordPlusGAMMA-LACTAMS-
dc.subject.keywordPlusISOMERIZATION-
dc.subject.keywordPlusAMINATION-
dc.subject.keywordPlusMIGRATION-
dc.subject.keywordPlusKINETICS-
dc.subject.keywordPlusINDOLES-
dc.subject.keywordPlusARYL-
dc.subject.keywordPlusAZIDES-
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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